A powerful technique with broad applications, operando X-ray absorption spectroscopy (XAS) is widely used but there is a lack of design and reporting standards. Focusing on water-splitting electrocatalysts, we propose best practices for the reproducibility, replicability and reliability of operando XAS studies.
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References
Fabbri, E. et al. Nat. Mater. 16, 925–931 (2017).
Risch, M. et al. J. Phys. Chem. C 117, 8628–8635 (2013).
Diklić, N. et al. ACS Energy Lett. 7, 1735–1740 (2022).
Diercks, J. S. et al. Angew. Chem. Int. Ed. 62, e202216633 (2023).
Binninger, T. et al. J. Electrochem. Soc. 163, H906 (2016).
Diercks, J. S. et al. ACS Catal. 12, 10727–10741 (2022).
Yang, Y. et al. J. Am. Chem. Soc. 141, 1463–1466 (2019).
Leonard, N. et al. Chem. Sci. 9, 5064–5073 (2018).
Beall, C. E. et al. EcoMat 5, e12353 (2023).
Nong, H. N. et al. Nature 587, 408–413 (2020).
Ebner, K. et al. Adv. Energy Mater. 12, 2103699 (2022).
Clark, A. H. et al. J. Synchrotron Radiat. 27, 681–688 (2020).
Kim, B.-J. et al. J. Am. Chem. Soc. 141, 5231–5240 (2019).
Diklić, N. et al. ACS Catal. 13, 11069–11079 (2023).
Timoshenko, J. & Cuenya, B. R. Chem. Rev. 121, 882–961 (2021).
Acknowledgements
E.F. gratefully acknowledges the Swiss National Science Foundation through its PRIMA grant (grant no. PR00P2_193111). T.J.S. thanks the Swiss Center of Excellence on Net Zero Emissions.
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Clark, A.H., Schmidt, T.J. & Fabbri, E. Best practices for operando hard X-ray absorption spectroscopy. Nat Sustain (2024). https://doi.org/10.1038/s41893-024-01322-w
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DOI: https://doi.org/10.1038/s41893-024-01322-w