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Please quote Nature Materials as the source of these items.

December 2002

Nanotube-reinforced ceramics

Single-wall carbon nanotubes are the toughest fibres known, and structural materials that incorporate nanotubes could have superior properties. Although researchers have developed tough nanotube-reinforced polymer composites, work on ceramic composites has proceeded more slowly. In the January 2003 issue of Nature Materials, Guo-Dong Zhan and colleagues at the University of California report a carbon nanotube/alumina nanocomposite with over twice the toughness of pure nanocrystalline alumina.

To prepare their high-toughness composites, the researchers used a technique called spark-plasma sintering (SPS). Unlike other sintering methods, SPS allows sintering of the nanotube-ceramic powder at relatively low temperatures, which means that the single-wall nanotubes are not damaged during the process. The high quality of the single-wall nanotubes and alumina powder used in the synthesis also contribute to the superior properties of the nanocomposite.

In contrast to previous work on nanotube-ceramic composites, the fracture toughness was found to increase with nanotube density. This is thought to be due to the formation of entangled networks of single-wall carbon nanotubes, which may prevent cracks developing. Further studies of the microstructure and mechanical properties are in progress, but this initial work indicates that entangled ropes of single-wall nanotubes are very promising materials for reinforcing nanostructured ceramic materials.

Single-wall carbon nanotubes as attractive toughening agents in alumina-based nanocomposites pp38-42

Guo-dong Zhan, Joshua D. Kuntz, Julin Wan and Amiya K. Mukherjee

Published online: 1 August 2004 | doi 10.1038/nmat793

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