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| Open AccessNarrowband room temperature phosphorescence of closed-loop molecules through the multiple resonance effect
Luminescent materials with narrowband emissions are vital for optoelectronic applications. Here, the authors achieve room temperature phosphorescence with a FWHM of 30 nm through the multiple resonance effect and showcase its practical application in X-ray imaging.
- Xiaokang Yao
- , Yuxin Li
- & Zhongfu An
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Article
| Open AccessQuantum barriers engineering toward radiative and stable perovskite photovoltaic devices
Efficient radiation is essential to reach thermodynamic limit of photovoltaic efficiency. Here, authors design thick quantum barriers to suppress interfacial quenching and boost photon recycling in perovskite cells, achieving high radiation and photovoltaic efficiencies and long device stability.
- Kyung Mun Yeom
- , Changsoon Cho
- & Jun Hong Noh
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Article
| Open AccessThe impact of magnesium content on lithium-magnesium alloy electrode performance with argyrodite solid electrolyte
All-solid-state lithium-based batteries require high stack pressure during operation. Here, we investigate the mechanical, transport, and interfacial properties of Li-rich magnesium alloy and show enhanced performance at low pressure and ambient temperature for alloy-based electrodes with less than 5 at% Mg content.
- Jack Aspinall
- , Krishnakanth Sada
- & Mauro Pasta
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Article
| Open AccessReconfigurable image processing metasurfaces with phase-change materials
Researchers demonstrate that image-processing metasurfaces can be dynamically reconfigured by using phase-change materials. The work might lead to novel tunable devices for compact optical computing for applications in AR/VR and bio-medical imaging.
- Michele Cotrufo
- , Shaban B. Sulejman
- & Andrea Alù
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Article
| Open AccessElectrostatically controlled spin polarization in Graphene-CrSBr magnetic proximity heterostructures
The electrostatic control of magnetic properties is central for future development of spintronic devices. Here, the authors show that the magnetic proximity effect induces an exchange shift in the band structure of graphene interfaced with CrSBr.
- Boxuan Yang
- , Bibek Bhujel
- & Bart J. van Wees
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Article
| Open AccessAbove-room-temperature chiral skyrmion lattice and Dzyaloshinskii–Moriya interaction in a van der Waals ferromagnet Fe3−xGaTe2
There are now several van der Waals magnets that have been shown to host skyrmions, however, these are typically hampered by a low Curie temperature, restricting the temperature at which the skyrmions can exist. Here, Zhang, Jiang, Jiang and coauthors find a skyrmion lattice in the van der Waals magnet Fe3 − xGaTe2 above room temperature and demonstrate the critical role of symmetry breaking in crystal lattice in the origin of these skyrmions.
- Chenhui Zhang
- , Ze Jiang
- & Hyunsoo Yang
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Article
| Open AccessEnhancement of phase transition temperature through hydrogen bond modification in molecular ferroelectrics
The authors propose a hydrogen bond modification method to achieve introduction of polarization and enhancement of phase transition temperature in molecular ferroelectrics, exploring the piezoelectric prototype devices of the molecular ferroelectric.
- Yu-An Xiong
- , Sheng-Shun Duan
- & Yu-Meng You
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Article
| Open AccessIntelligent wearable olfactory interface for latency-free mixed reality and fast olfactory enhancement
Liu et al. developed AI-driven, wearable olfactory interfaces with odor generators for realizing latency-free mixed-reality and fast olfaction recovery. This technology enables personalized olfactory feedback and enhanced virtual environments for various applications including education, and clinical treatment.
- Yiming Liu
- , Shengxin Jia
- & Xinge Yu
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Article
| Open AccessSynergetic regulation of SEI mechanics and crystallographic orientation for stable lithium metal pouch cells
The application of Li-metal batteries (LMBs) is impeded by unstable solid electrolyte interphase (SEI) and uncontrollable Li dendrites growth. Here, the authors present an YF3/PMMA composite layer to achieve high-performance LMBs via the synergetic regulation of SEI mechanics and Li crystallography.
- Yanhua Zhang
- , Rui Qiao
- & Jiangxuan Song
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Article
| Open AccessHumidity-tolerant porous polymer coating for passive daytime radiative cooling
A consistency issue with the production of porous polymer-based radiative coatings can be a significant drop in the cooling performance when dried under humid conditions. This issue is efficiently resolved by adding polymer reinforcement.
- Dongpyo Hong
- , Yong Joon Lee
- & Sang Yoon Park
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Article
| Open AccessSteering and cloaking of hyperbolic polaritons at deep-subwavelength scales
Polaritons – hybrid light-matter excitations – in van der Waals materials hold promise for photonics applications below the diffraction limit. Here, the authors demonstrate in-plane steering and cloaking of phonon polaritons in assembled micro-structures based on α-MoO3 films with misaligned crystallographic orientations.
- Hanchao Teng
- , Na Chen
- & Qing Dai
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Article
| Open AccessRevealing the hidden structure of disordered materials by parameterizing their local structural manifold
The structure of crystalline materials plays a central role in materials science, but the disordered structure of metallic glass is difficult to characterize and describe. Here, the authors use diffusion maps on atomistic data to obtain general structural descriptors tied to atomic positions.
- Thomas J. Hardin
- , Michael Chandross
- & Michael D. Shields
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Article
| Open AccessSpider-silk-inspired strong and tough hydrogel fibers with anti-freezing and water retention properties
Hydrogel fibres have potential in a range of applications such as flexible electronics, but achieving the desired mechanical properties can be challenging. Here, the authors report spider silk-inspired hydrogel fibres with tuneable mechanical properties suitable for flexible electronics.
- Shaoji Wu
- , Zhao Liu
- & Yurong Yan
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Article
| Open AccessRemarkable flexibility in freestanding single-crystalline antiferroelectric PbZrO3 membranes
Authors find that freestanding single crystalline antiferroelectric PbZrO3 membranes exhibit remarkable flexibility that can endure a maximum bending strain of 3.5%, with the assistance of mechanical-induced antiferroelectric-ferroelectric phase transition.
- Yunting Guo
- , Bin Peng
- & Ming Liu
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Article
| Open AccessMolecular orbital breaking in photo-mediated organosilicon Schiff base ferroelectric crystals
Switchable structural and physical bistability in ferroelectric materials can be achieved as result of molecular orbital breaking. Here, the authors describe the photo-mediated bistability in organosilicon Schiff base ferroelectric crystals for the modulation of dielectric, second-harmonic generation, and ferroelectric polarization and showing good in vitro biocompatibility.
- Zhu-Xiao Gu
- , Nan Zhang
- & Han-Yue Zhang
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Article
| Open AccessTunnel junctions based on interfacial two dimensional ferroelectrics
The authors study tunneling junctions in rhombohedral MoS2 bilayers and correlate their performance with the local domain layout. They show that the switching behavior in sliding ferroelectrics is strongly dependent on the pre-existing domain structure.
- Yunze Gao
- , Astrid Weston
- & Roman Gorbachev
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Article
| Open AccessUnusual facet and co-catalyst effects in TiO2-based photocatalytic coupling of methane
Designing photocatalysts to enhance the efficiency of non-oxidative coupling of methane is a challenging task. Here, the authors report that the anatase TiO2 with exposed {101} facets and Pd co-catalyst enables efficient and selective methane coupling to ethane via a heterogeneous-homogeneous hybrid reaction pathway.
- Huizhen Zhang
- , Pengfei Sun
- & Ye Wang
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Article
| Open AccessHighly porous metal-organic framework liquids and glasses via a solvent-assisted linker exchange strategy of ZIF-8
The canonical metal-organic framework ZIF-8 does not melt and form a glass. Here, authors incorporated two additional organic linkers into ZIF-8 to generate meltable derivatives which can be transformed into highly porous glasses by melt-quenching.
- Wen-Long Xue
- , Pascal Kolodzeiski
- & Sebastian Henke
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Article
| Open AccessAn inorganic-blended p-type semiconductor with robust electrical and mechanical properties
The authors report an inorganic tellurium-selenium-oxygen (TeSeO) alloyed semiconductor for high-mobility p-channel transistors and broadband photodetectors, through the scalable thermal evaporation method combined with post-oxygen implantation.
- You Meng
- , Weijun Wang
- & Johnny C. Ho
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Article
| Open AccessTransparent radiative cooling cover window for flexible and foldable electronic displays
In this work, authors synthesize transparent radiative cooling cover windows for flexible and foldable electronic devices. Besides demonstrated enhanced mechanical and moisture-impermeable properties, these mitigate temperature rise of devices under solar irradiation and improve overall thermal management.
- Kang Won Lee
- , Jonghun Yi
- & Dong Rip Kim
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Article
| Open AccessUrea-formaldehyde resin room temperature phosphorescent material with ultra-long afterglow and adjustable phosphorescence performance
Organic room temperature phosphorescent materials have useful properties, but development can be limited by processing and stability challenges. Here, the authors report a derivatisation strategy for the preparation of room temperature phosphorescent materials responsive to an electrostatic field.
- Wensheng Xu
- , Bowei Wang
- & Ligong Chen
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Article
| Open AccessDirect observation of electron transfer in solids through X-ray crystallography
Electron transfer in solids is a fundamental process in many functional nanomaterials. Here, the authors directly observe this process via x-ray crystallography for incorporating of electron-donor guest molecules in macrocyclic nanotube crystals.
- Daiji Ogata
- , Shota Koide
- & Junpei Yuasa
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Article
| Open AccessStable pure-green organic light-emitting diodes toward Rec.2020 standard
It is essential to manipulate the dynamic behaviour of charge carriers and excitons in organic light-emitting diodes. Here, authors report the trapping of injected electrons by a thermally activated delayed fluorescence assistant molecule in a bipolar host matrix and achieve long device stability.
- Xun Tang
- , Tuul Tsagaantsooj
- & Chihaya Adachi
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Article
| Open AccessOrbital-dependent electron correlation in double-layer nickelate La3Ni2O7
Recently, superconductivity near 80 K was observed in La3Ni2O7 under high pressure, but the mechanism is debated. Here the authors report angle-resolved photoemission spectroscopy measurements under ambient pressure, revealing flat bands with strong electronic correlations that could be linked to superconductivity.
- Jiangang Yang
- , Hualei Sun
- & X. J. Zhou
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Article
| Open AccessHighly tunable ground and excited state excitonic dipoles in multilayer 2H-MoSe2
Here, the authors discover the ground and excited state interlayer excitons in bi- and tri-layer 2H-MoSe2 crystals which exhibit electric-field-driven hybridisation with the intralayer A excitons, showing distinct spin, layer and valley characteristics.
- Shun Feng
- , Aidan J. Campbell
- & Brian D. Gerardot
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Article
| Open AccessReal-time observation of two distinctive non-thermalized hot electron dynamics at MXene/molecule interfaces
Photoexcited MXenes could transfer charge carriers to or heat molecules at their interfaces. Here, the authors show using time-resolved spectroscopy that the non-thermalized carriers can directly transfer to molecules or heat them within 125 fs.
- Qi Zhang
- , Wei Li
- & Xueming Yang
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Article
| Open AccessNylons with Highly-Bright and Ultralong Organic Room-Temperature Phosphorescence
It may be useful to obtain nylon with room temperature phosphorescence, but identifying a suitable luminophore is challenging. Here, the authors report the doping of nylon with cyano-substituted benzimidazole derivatives for room temperature phosphorescent nylons.
- Dian-Xue Ma
- , Zhong-Qiu Li
- & Yu-Wu Zhong
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Perspective
| Open AccessRediscovery of mononuclear phagocyte system blockade for nanoparticle drug delivery
Temporal blockade of the mononuclear phagocyte system is an approach to enhance the therapeutic efficiency of nanocarrier drug-delivery systems but the broad applicability is hindered by the complexity of optimisation and management of potential side effects. Here, the authors review the development of this technique and show its efficiency using meta-analysis of the published data and discuss essential features for its successful translation to clinic.
- Ivan V. Zelepukin
- , Konstantin G. Shevchenko
- & Sergey M. Deyev
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Article
| Open AccessGeneral synthesis of ionic-electronic coupled two-dimensional materials
2D AMX2 compounds (where A is a monovalent metal ion, M is a trivalent metal, and X is a chalcogen) are a family of materials with coupled ionic-electronic properties. Here, the authors report a chemical vapor deposition strategy to fabricate 20 types of 2D AMX2 flakes, exhibiting superionic conductivity or room temperature ferroelectricity.
- Xiang Xu
- , Yunxin Chen
- & Tianyou Zhai
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Article
| Open AccessEmergent disorder and mechanical memory in periodic metamaterials
Frustrated magnetic systems typically have multiple ground state configurations. While such multistability is common in amorphous materials, periodic mechanical systems have long range elastic interactions that tend to lead to a long-range ordered ground state. Herein, Sirote-Katz, Shohat et al. introduce periodic mechanical systems that have many disordered metastable states.
- Chaviva Sirote-Katz
- , Dor Shohat
- & Yair Shokef
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Article
| Open AccessLightweight and drift-free magnetically actuated millirobots via asymmetric laser-induced graphene
Millirobots effective application generally depends on cost, scalability, efficient locomotion, and the ability to track target trajectory precisely. Here, authors demonstrate promising graphene-based helical millirobots by introducing asymmetric light pattern distortion to a laser-induced graphene process.
- Yun Chen
- , Yuanhui Guo
- & Ni Zhao
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Article
| Open AccessPd(II)/Pd(IV) redox shuttle to suppress vacancy defects at grain boundaries for efficient kesterite solar cells
Charge loss at grain boundaries of kesterite polycrystalline absorbers limits the performance of thin film solar cells. Here, authors report the use of Pd(II)/Pd(IV) redox shuttle to assist the capture and exchange of Se atoms and eliminate vacancy defects, realizing certified efficiency of 14.3%.
- Jinlin Wang
- , Jiangjian Shi
- & Qingbo Meng
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Article
| Open AccessLaCl3-based sodium halide solid electrolytes with high ionic conductivity for all-solid-state batteries
The advancement of sodium halide solid-state electrolytes can propel high-energy-density all-solid-state sodium-ion batteries. Here, the authors present a LaCl3-based electrolyte facilitating rapid Na+ ion conduction along the c-axis diffusion channel, ensuring high capacity even at elevated current densities.
- Chengyu Fu
- , Yifan Li
- & Hongfa Xiang
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Article
| Open AccessHighly reversible zinc metal anode enabled by strong Brønsted acid and hydrophobic interfacial chemistry
Trace amounts of strong acid can suppress Zn corrosion and promote uniform Zn deposition. Here, the authors use HTFSI to create a hydrophobic micro-environment at the Zn-electrolyte interface, enabling high efficiency and cycling stability.
- Qingshun Nian
- , Xuan Luo
- & Xiaodi Ren
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Article
| Open AccessPhysics-informed neural network for lithium-ion battery degradation stable modeling and prognosis
Reliable lithium-ion battery health assessment is vital for safety. Here, authors present a physics-informed neural network for accurate and stable state-of-health estimation, overcoming challenges of varied battery types and usage conditions.
- Fujin Wang
- , Zhi Zhai
- & Xuefeng Chen
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Article
| Open AccessModulate stress distribution with bio-inspired irregular architected materials towards optimal tissue support
Natural materials exhibit compelling functionalities owing to their irregular architectures, but the study on irregular architected materials is elusive. Here the authors report a generative computational framework to virtually grow irregular materials with optimized properties that match target stress distributions, facilitating tissue support for orthopedic femur restoration.
- Yingqi Jia
- , Ke Liu
- & Xiaojia Shelly Zhang
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Article
| Open AccessSuperlative mechanical energy absorbing efficiency discovered through self-driving lab-human partnership
It is challenging to design tough structures based on energy absorbing efficiency owing to the difficulties in modeling non-linear deformation. Here, the authors report a human-monitored self-driving lab and discover structural motifs with high energy absorbing efficiencies up to 75.2%.
- Kelsey L. Snapp
- , Benjamin Verdier
- & Keith A. Brown
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Article
| Open AccessThe role of microstructure in the thermal fatigue of solder joints
Thermal fatigue frequently leads to failure in electronic solder joints. Here, the authors measure and quantitatively explain how microstructure affects thermal fatigue in a ball grid array package and propose optimum microstructures for thermal fatigue resistance.
- J. W. Xian
- , Y. L. Xu
- & C. M. Gourlay
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Article
| Open AccessNon-coplanar helimagnetism in the layered van-der-Waals metal DyTe3
Helimagnetic materials host a twisted magnetic texture, realizing screws, cycloids, and cones. While helimagnets are common in three dimensional materials, layered van der Waals helimagnets are exceedingly rare. Here, Akatsuka et al. demonstrate conical ordering in the easily cleavable magnet DyTe3.
- Shun Akatsuka
- , Sebastian Esser
- & Max Hirschberger
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Article
| Open AccessConcentration-induced spontaneous polymerization of protic ionic liquids for efficient in situ adhesion
Adhesives require a balance between cohesion and interfacial adhesion, which can be challenging to achieve. Here the authors report the polymerisation of a protic ionic liquid-based monomer, with internal and external non-covalent interactions contributing to both cohesion and adhesion.
- Jun Zhang
- , Xuan Zhou
- & Shiguo Zhang
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Article
| Open AccessBounds to electron spin qubit variability for scalable CMOS architectures
Understanding the microscopic variability of CMOS spin qubits is crucial for developing scalable quantum processors. Here the authors report a combined experimental and numerical study of the effect of interface roughness on variability of quantum dot spin qubits formed at the Si/SiO2 interface.
- Jesús D. Cifuentes
- , Tuomo Tanttu
- & Andre Saraiva
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Article
| Open AccessPolarization-driven band topology evolution in twisted MoTe2 and WSe2
The band topology of twisted 2D systems is a key factor behind their fascinating physics. Here, the authors demonstrate the role of polarization in driving the band topology evolution in twisted transition metal dichalcogenide homobilayers.
- Xiao-Wei Zhang
- , Chong Wang
- & Di Xiao
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Article
| Open AccessDroplet-based mechanical transducers modulated by the symmetry of wettability patterns
Asymmetric mechanical transducers are pivotal in various applications; however, conventional methods demand continuous energy and intricate fabrication. Here, the authors demonstrate a droplet-based mechanical transducer utilizing wettability-patterned surfaces, enabling precise control of droplet dynamics.
- Luanluan Xue
- , An Li
- & Yanlin Song
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Article
| Open AccessA large-strain and ultrahigh energy density dielectric elastomer for fast moving soft robot
Dielectric elastomer actuators require high driving electric fields to achieve high performances for soft robots due to their low dielectric constant and high stiffness. Here, the authors introduce polar fluorinated groups and nanodomains aggregated by long alkyl side chains into the dielectric elastomer design to overcome these issues and develop fast soft robots.
- Wenwen Feng
- , Lin Sun
- & Chao Wang
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Article
| Open AccessAtomically dispersed Iridium on Mo2C as an efficient and stable alkaline hydrogen oxidation reaction catalyst
High-performance hydroxide exchange membrane fuel cells rely on the anode loading of platinum-group metals. Here, the authors report a highly active hydrogen oxidation electrocatalyst which contains atomically dispersed Ir on Mo2C nanoparticles supported on a carbon substrate.
- Jinjie Fang
- , Haiyong Wang
- & Zhongbin Zhuang
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Article
| Open AccessExtreme magnetoresistance at high-mobility oxide heterointerfaces with dynamic defect tunability
Extreme magnetoresistance is characterized by a large and non-saturating magnetoresistance. Typically, it is observed in materials with compensated bandstructures, however, here, Christensen et al demonstrate a large and non-saturating magnetoresistance in a γAl2O3/SrTiO3 heterostructure, which is related to disorder, rather than the materials bandstructure.
- D. V. Christensen
- , T. S. Steegemans
- & N. Pryds
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Article
| Open AccessEvidence for multiferroicity in single-layer CuCrSe2
The authors observe multiferroicity in a single-layer non van der Waals material, CuCrSe2. The coexistence of room-temperature ferroelectricity and ferromagnetism up to 120 K is corroborated by a set of comprehensive experimental techniques.
- Zhenyu Sun
- , Yueqi Su
- & Baojie Feng
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Article
| Open AccessHigh spin axion insulator
Existing proposals of axion insulators are limited to spin-1/2 systems. Here the authors put forward a concept of a high spin axion insulator with several peculiar properties, such as the absence of gapless surface states and tunability of the axion field by an external magnetic field.
- Shuai Li
- , Ming Gong
- & X. C. Xie
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Article
| Open AccessHigh-performance flexible p-type Ce-filled Fe3CoSb12 skutterudite thin film for medium-to-high-temperature applications
The authors fabricate p-type Fe3CoSb12-based skutterudite films exhibiting high thermoelectric performance, stability, and flexibility at medium-to-high temperatures, based on preparing custom target materials and pulsed laser deposition techniques.
- Dou Li
- , Xiao-Lei Shi
- & Zhi-Gang Chen