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Stiffening hydrogels to probe short- and long-term cellular responses to dynamic mechanics
Studying the effects of extracellular matrix stiffening has been impeded because mostin vitromodels are static. Here, dynamic hydrogels are developed that stiffen in the presence of cells and are used to investigate the short-term (minutes-to-hours) and long-term (days-to-weeks) cellular responses to dynamic stiffening.
- Murat Guvendiren
- & Jason A. Burdick
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| Open AccessStrong-coupling d-wave superconductivity in PuCoGa5 probed by point-contact spectroscopy
The heavy-fermion material PuCoGa5 is characterized by unconventional superconducting properties. By combining point-contact spectroscopy and first-principles calculations, this study reveals a d-wave symmetry in the system's order parameter.
- D. Daghero
- , M. Tortello
- & R. Caciuffo
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Atomic-scale evolution of modulated phases at the ferroelectric–antiferroelectric morphotropic phase boundary controlled by flexoelectric interaction
Morphotropic phase boundaries—regions of abrupt structural change and enhanced material response—are of practical importance and are a challenge for the fundamental theory of phase transitions. Here, the ferroelectric–antiferroelectric boundary is studied using atomically resolved mapping in BiFeO3.
- A.Y. Borisevich
- , E.A. Eliseev
- & S.V. Kalinin
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| Open AccessUltrathin and lightweight organic solar cells with high flexibility
Organic solar cells are promising for technological applications, as they are lightweight and mechanically robust. This study presents flexible organic solar cells that are less than 2 μm thick, have very low specific weight and maintain their photovoltaic performance under repeated mechanical deformation.
- Martin Kaltenbrunner
- , Matthew S. White
- & Siegfried Bauer
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Dark acoustic metamaterials as super absorbers for low-frequency sound
Metamaterials can be used to alter the transmission of light or sound, with their tailored structures permitting control over their optical or acoustic properties. Meiet al. present a thin-film acoustic metamaterial that provides efficient absorption of sound over a broad range of wavelengths.
- Jun Mei
- , Guancong Ma
- & Ping Sheng
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Graphene-based wireless bacteria detection on tooth enamel
Graphene is characterized by unique physical properties that offer substantial promise, most notably for electronic applications. Mannooret al. present a wireless graphene-based sensor for detecting bacteria on a range of biological tissues.
- Manu S. Mannoor
- , Hu Tao
- & Michael C. McAlpine
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Giant spin-dependent thermoelectric effect in magnetic tunnel junctions
The spin-dependent thermal and electrical transport properties of nanostructures are central for future applications of spintronic devices. Here, Linet al. report an enhanced spin-dependent thermoelectric effect in an Al2O3-based magnetic tunnel junction.
- Weiwei Lin
- , Michel Hehn
- & Stéphane Mangin
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| Open AccessEnhanced electromechanical response of ferroelectrics due to charged domain walls
The piezoelectric materials most commonly used for technological applications contain lead, a toxic element. Slukaet al. identify a mechanism that leads to an enhancement of the dielectric and piezoelectric properties of non-toxic ferroelectrics, due to the presence of charged domain walls.
- Tomas Sluka
- , Alexander K. Tagantsev
- & Nava Setter
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Probing charge scattering mechanisms in suspended graphene by varying its dielectric environment
A factor limiting the mobility of charge carriers in graphene, and therefore its use in electronic applications, is the Coulomb scattering due to charged impurities. By exposing graphene devices to a range of non-polar liquids, Newazet al. observe an enhancement of the mobility due to screening.
- A.K.M. Newaz
- , Yevgeniy S. Puzyrev
- & Kirill I. Bolotin
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Integrated photosystem II-based photo-bioelectrochemical cells
The photosynthetic reaction centres, photosystems I and II, have been investigated for the light-induced generation of fuels and electrical power. Now, Yehezkeliet al. report a photobiofuel cell that generates electricity upon irradiation of photosystem II-functionalized electrodes in aqueous solutions.
- Omer Yehezkeli
- , Ran Tel-Vered
- & Itamar Willner
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Observation of conducting filament growth in nanoscale resistive memories
Resistive switching devices are promising candidates for non-volatile memories. Usingin-situ and ex-situ transmission electron microscopy, Yang et al. present an extensive study of the dynamics of filaments forming across the electrodes of resisting switching devices known as electrochemical metallization memories.
- Yuchao Yang
- , Peng Gao
- & Wei Lu
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Perpendicular exchange bias in ferrimagnetic spin valves
Exchange bias is a technologically relevant effect that occurs when thin ferromagnetic films are placed in direct proximity to antiferromagnets. Raduet al. show that an exchange bias occurs at room temperature in ferrimagnetic trilayers, in which the magnetization is aligned perpendicular to the structures.
- F. Radu
- , R. Abrudan
- & H. Zabel
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Ultrafast changes in lattice symmetry probed by coherent phonons
Ultrafast excitation offers new routes to controlling material properties on short timescales, but probes are needed to better understand the changes. By studying the phonon spectrum of VO2 in the time domain, Wall et al. find a prompt change in lattice potential after a photoinduced structural transition.
- S. Wall
- , D. Wegkamp
- & M. Wolf
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| Open AccessCharge state manipulation of qubits in diamond
Point defects in diamond in the form of nitrogen vacancy centres are believed to be promising candidates for qubits in quantum computers. Grotzet al. present a method for manipulating the charge state of nitrogen vacancies using an electrolytic gate electrode.
- Bernhard Grotz
- , Moritz V. Hauf
- & Jose A. Garrido
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Organic transistors with high thermal stability for medical applications
Organic electronic devices are promising for many applications, particularly in biomedical research, but are hindered by thermal instability and low melting points. Now, organic thin-film transistors are shown with excellent thermal properties that can withstand medical sterilization processes.
- Kazunori Kuribara
- , He Wang
- & Takao Someya
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Room temperature ferromagnetism in Teflon due to carbon dangling bonds
Teflon is a carbon based polymer that cannot be intrinsically ferromagnetic. This study shows that room temperature ferromagnetism can be induced in Teflon tape by applying mechanical stress such as stretching or cutting, which gives rise to dangling carbon bonds.
- Y.W. Ma
- , Y.H. Lu
- & J. Ding
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| Open AccessSelf-assembly of amorphous calcium carbonate microlens arrays
Biological materials efficiently exploit self-assembly of simple constituents to produce complex functional structures such as optical devices. By controlling organic molecules, Leeet al. show fast two-step self-assembly of CaCO3microlens arrays, reminiscent of their biological counterparts.
- Kyubock Lee
- , Wolfgang Wagermaier
- & Peter Fratzl
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| Open AccessPrecise hierarchical self-assembly of multicompartment micelles
Multicompartment micelles can be assembled from block copolymers but it is difficult to manipulate their hierarchical superstructures using straightforward concepts. Here, methods are developed that involve the pre-assembly of subunits for the structurally controlled production of micelles.
- André H. Gröschel
- , Felix H. Schacher
- & Axel H.E. Müller
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| Open AccessZigzag line defects and manipulation of colloids in a nematic liquid crystal in microwrinkle grooves
Understanding defects in liquid crystals is important for controlling their structure and self-assembly properties. Here, nematic liquid crystals confined in microwrinkle grooves show new periodic arrangements and zigzag line defects that can trap particles, offering a method for colloid manipulation.
- Takuya Ohzono
- & Jun-ichi Fukuda
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| Open AccessRepeated growth and bubbling transfer of graphene with millimetre-size single-crystal grains using platinum
Grain boundaries in graphene degrade its properties, and large single-crystal graphene is desirable for electronic applications of graphene. Gaoet al. develop a method to produce millimetre-sized hexagonal single-crystal graphene grains, and films composed of the grains, on platinum by chemical vapour deposition.
- Libo Gao
- , Wencai Ren
- & Hui-Ming Cheng
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| Open AccessResolving the electromagnetic mechanism of surface-enhanced light scattering at single hot spots
Light scattering from nanoscale objects can be dramatically enhanced in the proximity of optical antennas. Here, by studying the amplitude and phase of the light scattered from a tip located at the hot spot of an antenna, the underlying electromagnetic mechanism of this enhancement is resolved.
- P. Alonso-González
- , P. Albella
- & R. Hillenbrand
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Fully inorganic oxide-in-oxide ultraviolet nanocrystal light emitting devices
Light-emitting diodes in the form of nanocrystals offer promise for environmental and biomedical diagnostics. Brovelliet al. present a method for realizing mechanically robust and chemically stable nanocrystals emitting light in the ultraviolet range.
- Sergio Brovelli
- , Norberto Chiodini
- & Alberto Paleari
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Wide bandgap tunability in complex transition metal oxides by site-specific substitution
Tuning the bandgap of complex transition metal oxides in a manner that preserves their intrinsic properties has so far remained elusive. Choiet al. demonstrate that the bandgap of bismuth titanate can be varied by substitutional alloying with lanthanum cobaltate, without altering its ferroelectric properties.
- Woo Seok Choi
- , Matthew F. Chisholm
- & Ho Nyung Lee
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Emergence of non-centrosymmetric topological insulating phase in BiTeI under pressure
The spin–orbit interaction affects the electronic structure of many solids to give rise to a host of unusual phenomena. Bahramyet al.theoretically examine its role in the non-centrosymmetric compound BiTeI, and find that under the application of pressure, it leads to topologically insulating behaviour.
- M.S. Bahramy
- , B.-J. Yang
- & N. Nagaosa
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| Open AccessCMOS-based carbon nanotube pass-transistor logic integrated circuits
Field-effect transistors fabricated from carbon nanotubes have been investigated extensively over the past two decades. This study demonstrates a nanotube-based integrated circuit design that substantially improves the speed and power consumption with respect to silicon-based integrated circuits.
- Li Ding
- , Zhiyong Zhang
- & Lian-Mao Peng
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Broadband light management using low-Q whispering gallery modes in spherical nanoshells
Control of light absorption in optical devices, such as solar cells, can be achieved through resonant features like whispering gallery modes. Here, these modes are exploited in spherical silicon nanoshells to enhance absorption over a broad spectral range in nanometre-scale flexible layers.
- Yan Yao
- , Jie Yao
- & Yi Cui
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| Open AccessSynergistic toughening of composite fibres by self-alignment of reduced graphene oxide and carbon nanotubes
Composite fibres made of polymers reinforced by carbon nanotubes are known for their exceptional toughness. Shinet al. make these composites even tougher, by self-aligning carbon nanotubes and reduced graphene oxide flakes within the polymer matrix.
- Min Kyoon Shin
- , Bommy Lee
- & Seon Jeong Kim
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Atom-specific spin mapping and buried topological states in a homologous series of topological insulators
Strategies to tune the surface properties of topological insulators are essential, if they are to find use in applications. Using a combination of theoretical and experimental techniques, this study examines how the properties of ordered ternary topological insulators vary with the content of group IV elements.
- Sergey V. Eremeev
- , Gabriel Landolt
- & Evgueni V. Chulkov
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Tunable Dirac cone in the topological insulator Bi2-xSbxTe3-ySey
The surface electronic structure of topological insulators is characterized by a so-called Dirac cone energy dispersion. This study shows that by tuning the compositions in the compound Bi2−xSbxTe3−ySeyone can control the precise features of its Dirac cone structure while keeping it a bulk insulator.
- T. Arakane
- , T. Sato
- & Yoichi Ando
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Chemical structures of hydrazine-treated graphene oxide and generation of aromatic nitrogen doping
Parket al. use 13C and 15N solid-state NMR and X-ray photoelectron spectroscopy to study the chemical structure of hydrazine-treated graphite oxide. Hydrazine treatment is shown to lead to the incorporation of aromatic N2moieties at the graphene edges and restore graphitic networks on the basal planes.
- Sungjin Park
- , Yichen Hu
- & Rodney S. Ruoff
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Near room-temperature synthesis of transfer-free graphene films
Current methods for fabricating graphene rely on its transfer from metal surfaces to substrates suitable for device applications. This study demonstrates a transfer-free approach for growing graphene on substrates such as thermally oxidized silicon and plastic that forms the material underneath a nickel film, at the nickel–substrate interface.
- Jinsung Kwak
- , Jae Hwan Chu
- & Soon-Yong Kwon
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| Open AccessGeometry analysis and systematic synthesis of highly porous isoreticular frameworks with a unique topology
Zhanget al. show that simple geometry analysis can be used to predict how linker length and length ratios affect pore shape and size of porous coordination polymers. The accuracy of the predictions is confirmed by the synthesis of a series of 13 highly porous isoreticular frameworks.
- Yue-Biao Zhang
- , Hao-Long Zhou
- & Xiao-Ming Chen
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| Open AccessObservation of the inverse spin Hall effect in silicon
The spin Hall effect is a spin current induced by an electric current, and its occurrence in semiconductors is a promising route to controlling spins and their transport. Here, the inverse spin Hall effect, in which an electric current is induced by a spin current, is observed in silicon for the first time.
- Kazuya Ando
- & Eiji Saitoh
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| Open AccessA cobalt complex redox shuttle for dye-sensitized solar cells with high open-circuit potentials
Dye-sensitized solar cells are a promising alternative to traditional inorganic semiconductor-based solar cells. Yumet al. use a molecularly engineered cobalt complex as a redox mediator to achieve an open-circuit voltage of over 1,000 mV in a mesoscopic dye-sensitized solar cell.
- Jun-Ho Yum
- , Etienne Baranoff
- & Michael Grätzel
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Momentum-dependent multiple gaps in magnesium diboride probed by electron tunnelling spectroscopy
The electronic structure of superconducting magnesium diboride is predicted theoretically to have a distribution of energy gap values. Chenet al. observe this distribution of values experimentally, by means of high-resolution electron tunnelling spectroscopy.
- Ke Chen
- , Wenqing Dai
- & X. X. Xi
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Mechanism of supercooled droplet freezing on surfaces
The mechanism through which ice forms on surfaces is of broad technological relevance. This study examines the manner in which ice forms on so-called 'icephobic' surfaces, and demonstrates that simple changes in the environmental conditions can render the icephobicity ineffective.
- Stefan Jung
- , Manish K. Tiwari
- & Dimos Poulikakos
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| Open AccessPhotoswitchable gel assembly based on molecular recognition
Self-assembly through molecular recognition events is used in the production of functionalized materials. This study shows that macroscopic gel assembly can be regulated through photoisomerization of an azobenzene moiety that interacts differently with two host molecules.
- Hiroyasu Yamaguchi
- , Yuichiro Kobayashi
- & Akira Harada
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| Open AccessApproaching the ideal elastic limit of metallic glasses
The elastic limit represents the maximum stress and strain a material can withstand and is well characterized in many crystalline solids, yet remains elusive for metallic glasses. Here, this limit is investigated in submicron metallic glass structures and is found to be twice as high as that of bulk samples.
- Lin Tian
- , Yong-Qiang Cheng
- & Evan Ma
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Metal-adeninate vertices for the construction of an exceptionally porous metal-organic framework
Metal‐organic framework (MOFs) with metal‐carboxylate cluster vertices and long, branched organic linkers are highly porous. Anet al. develop an alternative route to MOFs in which metal‐biomolecule clusters are used as vertices to construct a mesoporous MOF.
- Jihyun An
- , Omar K. Farha
- & Nathaniel L. Rosi
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Revealing the role of defects in ferroelectric switching with atomic resolution
Ferroelectric materials are characterized by a spontaneous polarization, which in practical applications is manipulated by an electric field. This study examines how defects affect the switching with atomic resolution, by usingin situaberration-corrected transmission electron microscopy.
- Peng Gao
- , Christopher T. Nelson
- & Xiaoqing Pan
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| Open AccessExtraordinary carrier multiplication gated by a picosecond electric field pulse
Studying carrier multiplication in materials is important to understand their transport properties and interaction with light. Hiroriet al. show that intense terahertz pulses can generate electron-hole pairs in GaAs quantum wells that then emit infrared light, contrary to the effect with a DC field.
- H. Hirori
- , K. Shinokita
- & K. Tanaka
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Inverse barocaloric effect in the giant magnetocaloric La–Fe–Si–Co compound
When materials change temperature as a result of the application of pressure or a change in the magnetization, they are said to display a barocaloric or magnetocaloric effect, respectively. This study reports a substantial barocaloric effect in the giant magnetocaloric material LaFe11.33Co0.47Si1.2.
- Lluís Mañosa
- , David González-Alonso
- & Subham Majumdar
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Interface engineering of quantum Hall effects in digital transition metal oxide heterostructures
Topological insulators are a class of materials with an unusual band structure that makes them metallic at the surface and insulating in the bulk. Okamoto and co-workers use electronic structure calculations to predict a new family of possible topological insulators based on transition-metal oxides.
- Di Xiao
- , Wenguang Zhu
- & Satoshi Okamoto
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| Open AccessStable prenucleation mineral clusters are liquid-like ionic polymers
Prenucleation clusters have been observed during the early stages of calcium carbonate formation, contrary to classical models. Here, computer simulations indicate that the clusters are composed of an ionic polymer with alternating calcium and carbonate ions, and a dynamic topology of chains, branches and rings.
- Raffaella Demichelis
- , Paolo Raiteri
- & Denis Gebauer
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Low-power nano-optical vortex trapping via plasmonic diabolo nanoantennas
Optical vortex traps are appealing for handling delicate particles, but conventional techniques are challenging with objects smaller than the diffraction limit of light. By exploiting plasmonic resonances in gold diabolo nanoantennas, Kanget al. demonstrate low-power vortex trapping of nano-scale objects.
- Ju-Hyung Kang
- , Kipom Kim
- & Hong-Gyu Park
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| Open AccessTandem synthesis of alternating polyesters from renewable resources
Biomass-derived monomers are a renewable resource for the production of polymers. Robertet al. develop an auto-tandem catalytic transformation for the synthesis of aliphatic polyesters—'activated' monomers are prepared from dicarboxylic acids, which can be copolymerized with epoxides.
- Carine Robert
- , Frédéric de Montigny
- & Christophe M. Thomas
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Rebalancing of internally generated carriers for mid-infrared interband cascade lasers with very low power consumption
Mid-infrared semiconductor lasers suffer from a high threshold power density, but interband cascade lasers may offer a more efficient alternative. Here, theory and experiments on such emitters demonstrate remarkably low thresholds and power consumption compared to state-of-the-art quantum cascade lasers.
- I. Vurgaftman
- , W.W. Bewley
- & J.R. Meyer
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Band structure engineering in (Bi1−xSbx)2Te3 ternary topological insulators
The unique band structure of topological insulators gives rise to insulating bulk and unusual metallic surface properties. By tuning the content of Sb in the ternary compound (Bi1–xSbx)2Te3, Wang and collaborators show it is possible to control the precise features of the band structure in a continuous fashion.
- Jinsong Zhang
- , Cui-Zu Chang
- & Yayu Wang
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Spin waves and magnetic exchange interactions in insulating Rb0.89Fe1.58Se2
Unlike the other iron-based superconductors, the parent compounds of the alkaline iron selenide superconductors are insulators. Dai and colleagues examine the spin-wave excitations in these materials and uncover evidence for a common magnetic origin for all iron-based superconductors.
- Miaoyin Wang
- , Chen Fang
- & Pengcheng Dai